URANIUM 101

1. What is Uranium?

Uranium is a radioactive element that occurs naturally in low concentrations (a few parts per million) in soil, rock, and surface and groundwater. It was discovered in 1789 by German chemist Martin Klaproth in the Joachimsal silver mines of the present day Czech Republic. In 1896 Polish-French physicist and chemist Maria Sklodowska-Curie discovered the radioactive properties of uranium.

Uranium in its pure form is a silver-colored heavy metal that is nearly twice as dense as lead. It is the heaviest naturally occurring element, with an atomic number of 92. In nature, uranium atoms exist as several isotopes: primarily uranium-238, uranium-235, and a very small amount of uranium-234. (Isotopes are different forms of an element that have the same number of protons in the nucleus, but a different number of neutrons.) In a typical sample of natural uranium, most of the mass (99.27%) consists of atoms of uranium-238. About 0.72% of the mass consists of atoms of uranium-235, and a very small amount (0.0055% by mass) is uranium-234.

2. Use of Uranium
Currently, the primary use of uranium is to fuel nuclear power reactors to generate electricity. For many years, uranium was used primarily as a colorant in ceramic glazes, producing colors that ranged from orange-red to lemon yellow. It was also used for tinting in early photography. Its potential for use as an energy source was realized only in the middle of the 20th century.
3. Uranium Exploration

Since uranium occurs in trace amounts (0.2-5.0ppm) in virtually all rocks, exploration for uranium is essentially the search for geological environments in which economic concentrations of uranium may have been produced. Uranium can take many chemical forms, but in nature it is generally found as an oxide. Triuranium oxtoxide (U308) is the most stable form of uranium oxide and is the form most commonly found in nature. Uranium exploration uses most techniques employed in the search for oil, gas and all other minerals, as well as some unique to uranium. Initial target areas are large, and, as smaller areas of potential are recognizsed, more intense methods are used. Geology, remote sensing, geophysics, geochemistry, geobotany and exploration drilling are all used at the same time.

Geological mapping and basin analysis helps in the choice of geological environments which are potentially favourable for uranium occurrences. Remote sensing using satellite imagery and aerial photography is used as part of this initial stage. Follow-up surveys using airborne or ground gamma-ray spectrometry to detect high-energy gamma radiation from the decay of radioactive minerals associated with uranium are used in the later stages of the exploration. Geochemical surveys of stream and lake sediments are commonly used to detect broad chemical anomalies and provide information on sub-surface environments. Stream and lake sediment surveys enable the systematic sampling of the uranium content of bedrock terrain over large areas and in any kind of vegetative and soil cover. Once a promising target is found, detailed exploration techniques are applied to carefully locate deposits, determine their size, shape and depth, and the concentration of uranium and other useful minerals. The techniques include the collection of geochemical and geophysical data from closely spaced locations as well as from drilling and the analysis of large samples. The final step is to see if it is possible to extract and separate the useful materials.

4. Location of Uranium Deposits

Uranium is found all over the world. The largest known deposits of uranium are found in Australia, Kazakhstan and Canada.

Source: Uranium 2005: Resources Production and Demand. OECD/IAEA. Based on identified resources which consists of reasonably assured resources and inferred resources at a cost of less than $80(US) per kilogram of uranium as at January 1, 2005.

5. Production of Uranium

Uranium is removed from the ground in of three methods depending on the characteristics of the deposit. The three methods are open pit mining, underground mining and in situ leach.

The open pit mining method is used to extract uranium when uranium ore is found near the surface, generally less than 100 metres deep. Soil and waste rock are removed to expose the hard rock. Then a pit is excavated to access the ore. The walls of the pit are mined in series of benches to prevent collapsing. The rock is broken by using explosives. The broken rock is hauled to the surface in large trucks for milling.

The underground mining method is usually used when uranium ore is located more than 100 metres below the surface. The ore is accessed by digging vertical shafts to the depth of the orebody. Then a number of tunnels are dug around the uranium deposit. In addition a number of horizontal tunnels are dug. These horizontal tunnels provide access to the mine and ventilation. The ore is blasted and hoisted to the surface for milling.

The in situ leaching method involves dissolving uranium either by pumping weak acid or carbonated water underground, bringing it back to the surface, and extracting the dissolved uranium. Certain geological conditions have to be present in order to use in situ leaching method. This method of productions is less labour intense. More and more uranium is produced by in situ leaching.
In 2006 production of Uranium was comprised of the following percentages of different methods:

Underground mining41%
Open pit mining24%
In situ leach (ISL)26%
By-product9%

(considering Olympic Dam as by-product rather than in underground category)

Canada produces the largest share of uranium from mines (25% of the world supply from mines), followed by Australia (19%) and Kazakhstan (13%).

Production from Mines by Country (tonnes U)

Country20022003200420052006
Canada116041045711597116289862
Australia68547572898295167593
Kazakhstan28003300371943575279
Niger30753143328230933434
Russia (est)29003150320034313262
Namibia23332036303831473067
Uzbekistan18601598201623002260
USA91977987810391672
Ukraine (est)800800800800800
China (est)730750750750750
South Africa824758755674534
Czech Repub.465452412408359
India (est)230230230230177
Brazil270310300110190
Romania (est)9090909090
Germany2121501507750
Pakistan (est3845454545
France200775
Total world3606335613402514170239429
tonnes U3O84252941998474684917946499
Source: World Nuclear Association
In 2006, the eight companies marketing most of the world's uranium mine production were:

Companytonnes U%
Cameco824920.9
Rio Tinto709418.0
Areva527213.4
KazAtomProm36999.4
TVEL32628.3
BHP Billiton28687.3
Navoi22605.7
Uranium One10002.5
Total top 833,70485.5
6. The Nuclear Fuel Cycle
After a successful exploration program, uranium ore undergoes several stages in its fuel cycle. Before uranium is used in a nuclear reactor, it undergoes the steps of mining and milling, conversion, enrichment and fuel fabrication. After uranium has been used in a reactor to produce electricity, it is known as 'spent fuel' and undergoes the further series of steps including temporary storage, reprocessing, and recycling before its eventual disposal as waste. Uranium ore undergoes:
  1. mining and milling to produce uranium ore concentrate known as yellowcake;
  2. conversion of the concentrated uranium into either uranium dioxide (UO2) for heavy water reactors or uranium hexafluoride for (UF6) for light water reactors;
  3. enrichment in which the proportion of the U-235 isotope is raised from the natural level of 0.7% to about 3.5%;
  4. fuel fabrication during which uranium is pressed into fuel pellets which are inserted into fuel rods;
  5. production of electricity where nuclear fuel is loaded into a reactor and allows nuclear reactions to produce steam which moves electricity generating turbines. Spent fuel assemblies taken from the reactor core are highly radioactive and give off a lot of heat. They are therefore stored in special ponds which are usually located at the reactor site, to allow both their heat and radioactivity to decrease;
  6. optional reprocessing of spent fuel, after a period of storage, to recover residual uranium and plutonium (Pu), both useful sources of energy, and to separate and package the highly radioactive residue produced which the fuel was in the reactor Spent fuel still contains approximately 96% of its original uranium, of which the fissionable U-235 content has been reduced to less than 1%. About 3% of spent fuel comprises waste products and the remaining 1% is plutonium produced while the fuel was in the reactor and not "burned" then. The remaining 3% of high-level radioactive wastes (some 750 kg per year from a 1000 MWe reactor) can be stored in liquid form and subsequently solidified.
  7. vitrification, where after reprocessing the liquid high-level waste can be calcined (heated strongly) to produce a dry powder which is incorporated into borosilicate (Pyrex) glass to immobilise the waste. The glass is then poured into stainless steel canisters, each holding 400 kg of glass. These can be readily transported and stored, with appropriate shielding;
  8. final disposal. The waste forms envisaged for disposal are vitrified high-level wastes sealed into stainless steel canisters, or spent fuel rods encapsulated in corrosion-resistant metals such as copper or stainless steel. The most widely accepted plans are for these to be buried in stable rock structures deep underground. Many geological formations such as granite, volcanic tuff, salt or shale will be suitable. The first permanent disposal is expected to occur about 2010.
7. Uranium Markets
Fuelling nuclear power plants is the main commercial use of uranium. Currently, nuclear power provides over 16% of the world's electricity, almost 24% of electricity in OECD countries, and 34% in the EU. Its use is increasing. Nuclear power is the most environmentally favourable way of producing electricity on a large scale. Without it most of the world would have to rely almost entirely on fossil fuels for base-load electricity production.
The present output of uranium comprises 61% of demand for power generation. In May of 2007 there were 437 nuclear power reactors in operation in the world. According to the World Nuclear Association, the particulars of the world nuclear power reactors and uranium requirements are as follows.

World Nuclear Power Reactors 2006-07 and Uranium Requirements

31 May 2007
NUCLEAR ELECTRICITY GENERATION 2006 REACTORS OPERABLE May 2007 REACTORS UNDER CONSTRUCTION May 2007 REACTORS PLANNED May 2007 REACTORS PROPOSED May 2007 URANIUM REQUIRED 2007
billion kWh % e No. MWe No. MWe No. MWe No. MWe tonnes U
Argentina 7.2 6.9 2 935 1 692 0 0 1 700 135
Armenia 2.4 42 1 376 0 0 0 0 1 1000 51
Belgium 44.3 54 7 5728 0 0 0 0 0 0 1079
Brazil 13 3.3 2 1901 0 0 1 1245 4 4000 338
Bulgaria 18.1 44 2 1906 0 0 2 1900 0 0 255
Canada* 92.4 16 18 12595 2 1540 4 4000 0 0 1836
China 51.8 1.9 11 8587 4 3170 23 24500 54 42000 1454
Czech Republic 24.5 31 6 3472 0 0 0 0 2 1900 550
Egypt 0 0 0 0 0 0 0 0 1 600 0
Finland 22 28 4 2696 1 1600 0 0 0 0 472
France 428.7 78 59 63473 0 0 1 1630 1 1600 10368
Germany 158.7 32 17 20303 0 0 0 0 0 0 3486
Hungary 12.5 38 4 1773 0 0 0 0 0 0 254
India 15.6 2.6 17 3779 6 2976 4 2800 15 11100 491
Indonesia 0 0 0 0 0 0 0 0 4 4000 0
Iran 0 0 0 0 1 915 2 1900 3 2850 143
Israel 0 0 0 0 0 0 0 0 1 1200 0
Japan 291.5 30 55 47577 2 2285 11 14945 1 1100 8872
Kazakhstan 0 0 0 0 0 0 0 0 1 300 0
Korea DPR (North) 0 0 0 0 0 0 1 950 0 0 0
Korea RO (South) 141.2 39 20 17533 1 950 7 8250 0 0 3037
Lithuania 8 69 1 1185 0 0 0 0 1 1000 134
Mexico 10.4 4.9 2 1310 0 0 0 0 2 2000 257
Netherlands 3.3 3.5 1 485 0 0 0 0 0 0 112
Pakistan 2.6 2.7 2 400 1 300 2 600 2 2000 64
Romania 5.2 9 1 655 1 655 0 0 3 1995 92
Russia 144.3 16 31 21743 5 2720 8 9600 18 21600 3777
Slovakia 16.6 57 5 2064 2 840 0 0 0 0 299
Slovenia 5.3 40 1 696 0 0 0 0 1 1000 145
South Africa 10.1 4.4 2 1842 0 0 1 165 24 4000 332
Spain 57.4 20 8 7442 0 0 0 0 0 0 1473
Sweden 65.1 48 10 9076 0 0 0 0 0 0 1468
Switzerland 26.4 37 5 3220 0 0 0 0 0 0 575
Turkey 0 0 0 0 0 0 3 4500 0 0 0
Ukraine 84.8 48 15 13168 0 0 2 1900 20 21000 2003
United Kingdom 69.2 18 19 10982 0 0 0 0 0 0 2021
USA 787.2 19 103 98254 1 1155 2 2716 21 24000 20050
Vietnam 0 0 0 0 0 0 0 0 2 2000 0
WORLD** 2658 16 437 370,040 30 22,398 74 81,601 182 151,345 66,529
Sources:
Reactor data: WNA to 31/05/07.
IAEA- for nuclear electricity production & percentage of electricity (% e) 5/07.
WNA: Global Nuclear Fuel Market (reference scenario) - for U.
Operating = Connected to the grid.
Building/Construction = first concrete for reactor poured, or major refurbishment under way.
Planned = Approvals and funding in place, or construction well advanced but suspended indefinitely.
Proposed = clear intention but still without funding and/or approvals.
TWh = Terawatt-hours (billion kilowatt-hours), MWe = Megawatt net (electrical as distinct from thermal), kWh = kilowatt-hour.
NB: 66,529 tU = 78,458 t U3O8
* In Canada, 'construction' figure is 2 laid-up Bruce A reactors.
** The world total includes 6 reactors on Taiwan with a combined capacity of 4884 MWe, which generated a total of 38.3 billion kWh in 2006
(accounting for 20% of Taiwan's total electricity generation). Taiwan has two reactors under construction with a combined capacity of 2600 MWe
8. Internet Sources about Uranium
The following websites provide useful information about uranium and nuclear energy in general:
Canadian Nuclear Association - http://www.cna.ca
Canadian Nuclear Safety Commission - http://www.nuclearsafety.gc.ca
International Atomic Energy Agency - http://www.iaea.org
The Nuclear Energy Agency - http://www.nea.fr
The Nuclear Energy Institute - http://www.nei.org
The World Nuclear Association - http://www.world-nuclear.org
Uranium Information Centre - http://www.uic.com.au
The Ux Consulting Company, LLC - http://www.uxc.com
The Depleted UF6 Management Information Network - http://web.ead.anl.gov/uranium/index.cfm
TradeTech - http://www.uranium.info
World Association of Nuclear Operators - http://www.wano.org.uk/

© 2007 ABBASTAR URANIUM CORP. All Rights Reserved.
For further information, please contact Gary Schroeder at
604-658-2040 or